Electrolyte-Free Dye-Sensitized Solar Cell with High Open Circuit Voltage Using a Bifunctional Ferrocene-Based Cyanovinyl Molecule as Dye and Redox Couple
journal contributionposted on 2018-06-19, 18:04 authored by A. Ghosh, S. Mishra, S. Giri, S. M. Mobin, A. Bera, S. Chatterjee
Functionalization of ferrocenyl moieties with a cyanovinyl system using a unique solid-state synthetic method led to the formation of donor–acceptor type compounds with wide absorption in the visible region. A DSSC study using the ferrocenyl cyanovinyl compound as a dye with an electrolyte-free fabrication system showed an unprecedented open-circuit voltage (VOC) of 763–841 mV. DFT calculations were carried out to understand an unique electron transfer mechanism for the DSSC device which may be responsible for the high VOC.
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moietieBifunctional Ferrocene-Based Cyanovinyl MoleculeDSSCFunctionalizationElectrolyte-Free Dye-Sensitized Solar Cellabsorptionelectron transfer mechanismcalculationelectrolyte-free fabrication systemtypemethodDFTmVformationdonordevicedyeHigh Open Circuit Voltageopen-circuitV OCregionvoltageferrocenyl cyanovinyl compoundRedox