posted on 2024-03-07, 12:14authored byJin-Feng Lv, Yang Deng, Xin-Yi Liang, Yu-Fang Tan, Yan-Hong He, Zhi Guan
The
electrochemical oxidative radical–radical cross-coupling
of sulfonyl hydrazides with diselenides for the synthesis of selenosulfonates
was successfully accomplished. The method is applicable to a wide
range of aromatic/aliphatic sulfonyl hydrazides and diselenides, providing
products in good to excellent yields. Notably, this protocol stands
out for its green and sustainable nature, as it does not rely on transition
metals and oxidizing agents, and the starting materials are cost-effective
and readily available.