posted on 2020-08-27, 15:41authored byTing-Ting Zhang, Mu-Jia Luo, Yang Li, Ren-Jie Song, Jin-Heng Li
A general, ideal atom utilization
electrochemical technology to
enable alkene alkoxyhalogenation and organohalide dehalogenation in
one pot is presented. This technology is highlighted by convergent
strategy integrating several reactions, such as alkene alkoxyhalogenation,
organohalide dehalogenation, and dehalogenation deuteration. Experimental
data suggest that alkenes have the lowest oxidation potential, which
lead to anodic conversion of the CC bond to the radical cation
intermediates, and cathodic transformations of organohalides, including
alkyl and aryl halides, as the nucleophilic halogen sources.