American Chemical Society
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Electrical Switch for Smart pH Self-Adjusting System Based on Silver Nanowire/Polyaniline Nanocomposite Film

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journal contribution
posted on 2015-03-24, 00:00 authored by Gui-Wen Huang, Hong-Mei Xiao, Shao-Yun Fu
A sensitive pH-triggered electrical switch is demonstrated by using a layer-structured silver nanowire/polyaniline nanocomposite film fabricated via an easy vertical spinning method. The as-prepared nanocomposite film shows the high electrical conductivity of 1.03 × 104 S cm–1 at the Ag-NW areal density of 0.84 mg cm–2 and a good cycling stability. Particularly, because of the layered structure, the switch achieves a very high contrast ratio of ca. 9 × 108, which is 2–6 orders higher than that reported previously. The high electrical conductivity and the high switching ratio make the layer-structured nanocomposite film a sensitive switch candidate for pH-responsive systems. Finally, a smart pH self-adjusting switching system is successfully designed using the as-prepared layer-structured nanocomposite film.