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Efficient Synthesis of α-Tertiary α-Silylamines from Aryl Sulfonylimidates via One-Pot, Sequential C–Si/C–C Bond Formations

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journal contribution
posted on 01.06.2012, 00:00 authored by Xiao-Jun Han, Ming Yao, Chong-Dao Lu
An efficient and flexible route for the synthesis of α-tertiary (α,α-dibranched) α-silylamines via sequential reactions of sulfonylimidates using readily available phenyldimethylsilyllithium and Grignard reagents is described. The procedure allows successive formation of C–Si/C–C bonds in a single flask.

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