posted on 2000-06-02, 00:00authored byBum Sung Lee, Shi Yong Lee, Dong Young Oh
Treatment of allylic and vinylic phosphonates with excess LiHMDS, followed by addition of
chlorotrimethylsilane, afforded α- and γ- silylated allylic phosphonate mixtures. Without separation,
these mixtures underwent the Friedel−Crafts reaction and base-promoted isomerization to give
4-oxo-2-alkenylphosphonates, which can serve as building blocks for the construction of polyethylenic
chains.