Direct ortho-Thiolation of Arenes
and Alkenes by Nickel Catalysis

Lin, Cong; Li, Danyang; Wang, Binjie; Yao, Jinzhong; Zhang, Yuhong

doi:10.1021/acs.orglett.5b00337.s001

ol5b00337_si_001.pdf (9.76 MB)

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Direct ortho-Thiolation of Arenes and Alkenes by Nickel Catalysis

journal contribution

posted on 2015-03-06, 00:00 authored by Cong Lin, Danyang Li, Binjie Wang, Jinzhong Yao, Yuhong Zhang

The direct thiolation of arenes and alkenes with diaryl disulfides was developed by nickel catalysis. The reaction displayed exceptional compatibility with a wide range of functional groups to regioselectively give the diaryl sulfides and alkenyl sulfides in high yields.