ol5b00337_si_001.pdf (9.76 MB)
Direct ortho-Thiolation of Arenes and Alkenes by Nickel Catalysis
journal contributionposted on 2015-03-06, 00:00 authored by Cong Lin, Danyang Li, Binjie Wang, Jinzhong Yao, Yuhong Zhang
The direct thiolation of arenes and alkenes with diaryl disulfides was developed by nickel catalysis. The reaction displayed exceptional compatibility with a wide range of functional groups to regioselectively give the diaryl sulfides and alkenyl sulfides in high yields.