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Direct Synthesis of the Phenanthroviridone Skeleton Using a Highly Regioselective Nitroquinone Diels–Alder Reaction

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journal contribution
posted on 17.04.2020, 20:45 by Huangchao Yu, Ellie L. Fought, Theresa L. Windus, George A. Kraus
A variety of nucleophiles react efficiently with in situ generated nitroquinones. The reaction with substituted resorcinols led to the direct synthesis of the phenanthroviridinone and lagumycin skeleton via a highly regioselective Diels–Alder reaction.