Direct EPR Observations of Both Oxidized and Reduced Porphyrin Dimers in
the Lowest Excited States:  A Novel Analysis of a Homobiradical with a
Strong Antiferromagnetic Interaction

Furuya, Fumio; Ishii, Kazuyuki; Kobayashi, Nagao

doi:10.1021/ja0201597.s001

Direct EPR Observations of Both Oxidized and Reduced Porphyrin Dimers in the Lowest Excited States: A Novel Analysis of a Homobiradical with a Strong Antiferromagnetic Interaction

journal contribution

posted on 2002-10-08, 00:00 authored by Fumio Furuya, Kazuyuki Ishii, Nagao Kobayashi

The oxidized and reduced forms of bis(tetra-tert-butyltetraazaporphinato)lutetium (III) (Lu(TAP)₂) have been examined by time-resolved EPR (TREPR) spectroscopy, showing both the first EPR investigation of a homobiradical with a strong antiferromagnetic interaction and usefulness of TREPR for investigating excited-state properties of different oxidation states.

History

Usage metrics

Keywords

oxidation states Novel Analysis EPR investigation Strong Antiferromagnetic Interaction III Reduced Porphyrin Dimers TREPR antiferromagnetic interaction Direct EPR Observations

Licence

CC BY-NC 4.0

Direct EPR Observations of Both Oxidized and Reduced Porphyrin Dimers in the Lowest Excited States: A Novel Analysis of a Homobiradical with a Strong Antiferromagnetic Interaction

History

Usage metrics

Categories

Keywords

Licence

Exports