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Direct Allylation of Quinones with Allylboronates

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journal contribution
posted on 20.03.2015, 00:00 by Hong-Ping Deng, Dong Wang, Kálmán J. Szabó
Allylboronates undergo C–H allylation of unsubstituted or monosubstituted benzoquinone and naphthoquinone substrates. In the case of 2,5- or 2,6-disubstituted quinones addition involving the substituted carbon takes place. Allylation with stereodefined allylboronates occurs with retention of the configuration.