Diastereoselective Aminooxygenation and Diamination
of Alkenes with Amidines by Hypervalent Iodine(III) Reagents

Chen, Hui; Kaga, Atsushi; Chiba, Shunsuke

doi:10.1021/ol503000c.s001

ol503000c_si_001.pdf (19.72 MB)

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Diastereoselective Aminooxygenation and Diamination of Alkenes with Amidines by Hypervalent Iodine(III) Reagents

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posted on 2014-12-05, 00:00 authored by Hui Chen, Atsushi Kaga, Shunsuke Chiba

Diastereoselective anti-aminooxygenation and anti-diamination of alkenes with amidines were enabled by hypervalent iodine(III) reagents such as PhI(OCOR)₂ and PhI(NMs₂)₂, respectively. The present transformation offers diastereochemically pure dihydroimidazoles divergently from E- and Z-alkenes.

Diastereoselective Aminooxygenation and Diamination of Alkenes with Amidines by Hypervalent Iodine(III) Reagents

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