posted on 2018-12-13, 00:00authored byStephen
J. A. DeWitt, Héctor Octavio Rubiera Landa, Yoshiaki Kawajiri, Matthew Realff, Ryan P. Lively
Microencapsulated phase change materials
(μPCM) are combined
with the metal–organic framework (MOF) UiO-66 and a cellulose
acetate fiber support to introduce thermal modulation into CO2 capture devices operating in subambient conditions. μPCM
particles are incorporated into sorbent fibers during the fiber spin
dope preparation step and are observed to withstand the spinning and
subsequent solvent exchange steps with little to no loss of thermal
modulating properties as determined by differential scanning calorimetry
(DSC). The spinning of this novel sorbent-μPCM fiber sorbent
is the first instance of single step spinning of sorbents with a thermal
modulator. It was found that μPCM weight loading as high as
75 wt % was attainable while maintaining spinable fibers. Breakthrough
adsorption experiments and subsequent temperature profile analysis
were collected to compare CO2 breakthrough capacity and
heat release for sorbent systems with and without phase change materials
incorporated. In adsorption modules with a diameter of 0.455 cm, where
heat dissipation through the module wall dominates the global thermal
response of the system, modulated fibers showed a 20–25% increase
in breakthrough capacity at short times (CO2 concentration C/C0 = 0.05) as compared to
their unmodulated counterparts. Higher breakthrough capacity indicates
the phase change material would help manage the heat effects due to
the local contact between the μPCM and the MOF. In larger diameter
modules (0.7 cm) where wall heat dissipation effects are less dominant
than the 0.455 cm diameter modules, fibers with “inactive”
μPCM (i.e., 50 °C below their melting point) show larger
sorption-induced thermal excursions and as much as 4× lower capacities
at low adsorbate leakage as compared to fibers where the phase change
material was active. Through the incorporation of phase change material,
the sorbent in the system acts more efficiently, thus potentially
driving down adsorption system cost.