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Development of General Catalytic Allylation of Acylhydrazones with Pinacolyl Allylboronate Using an Indium(I) Catalyst

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journal contribution
posted on 06.03.2008, 00:00 by Uwe Schneider, I-Hon Chen, Shū Kobayashi
Catalytic allylation of various acylhydrazones using a group 13 metal reagent (boron) in combination with a group 13 metal catalyst in its low-oxidation state (indium) has been developed. This operationally simple carbon−carbon bond-forming reaction displays remarkable substrate scope and functional group tolerance.