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Design of Novel Three-Dimensional Coordination Polymers Based on Triangular Trinuclear Copper 1,2,4-Triazolate Units

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journal contribution
posted on 07.06.2006, 00:00 by Quan-Guo Zhai, Can-Zhong Lu, Shu-Mei Chen, Xin-Jiang Xu, Wen-Bin Yang
By controlling the molar ratios of copper dichloride dihydrate and 1,2,4-triazole (trz), we generated a series of novel three-dimensional coordination polymers constructed from μ3-oxo or μ3-Cl triangular copper units, exhibiting six-connected porous self-penetrating net, graphite layer, and inorganic−organic hybrid network structures, respectively.