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Design and STM Investigation of Intramolecular Folding in Self-Assembled Monolayers on the Surface

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journal contribution
posted on 2004-11-03, 00:00 authored by Norbert Schuurmans, Hiroshi Uji-i, Wael Mamdouh, Frans C. De Schryver, Ben L. Feringa, Jan van Esch, Steven De Feyter
The rational design of catechol bis-amides rendered molecular structures that fold into β-turn mimics at the interface of HOPG and 1-octanol as demonstrated by STM. These self-assembled monolayers provide a prototypical model for linear sequences containing more turn mimics, which will allow for true synthetic surface confined foldamers.