ao0c01437_si_001.pdf (380.08 kB)
Deposition of Palladium Nanoparticles by the Coating of the Carbonaceous Layer from Wastepaper-Derived Bio-Oil
journal contributionposted on 2020-06-26, 02:29 authored by Tengyao Jiang, Yuan Yuan, Sijia Liu, Andrew J. Hunt, Gang Tan
A highly active and recyclable Pd-deposited catalyst has been successfully prepared for the Heck reaction. Bio-oil liquid, a byproduct from the microwave pyrolysis of wastepaper, is employed to immobilize palladium nanoparticles on a solid support. FTIR, GC, and NMR results indicate the self-polymerization feature of bio-oil, thus giving rise to a uniform carbonaceous layer coated around the surface of the catalyst. Characteristic analysis of the catalyst indicates that palladium nanoparticles are well-dispersed on the parent SBA-15 solid substrate, which is attributed to the carbonaceous layer that is derived from bio-oil carbonization, allowing a high catalytic performance as a heterogeneous catalyst for the Heck reaction. The as-synthesized catalyst demonstrates remarkable recyclability with firm deposition of palladium nanoparticles on the solid support and could be reused without a dramatic decrease in catalytic activity.