jo026367z_si_001.pdf (893.33 kB)
Deoxygenation of Dithiirane 1-Oxides with Lawesson's Reagent Leading to the Corresponding Dithiiranes
journal contributionposted on 2003-01-03, 00:00 authored by Akihiko Ishii, Remi Yamashita, Masashi Saito, Juzo Nakayama
3,3-Disubstituted dithiirane 1-oxides were efficiently reduced with Lawesson's reagent (LR) to give the corresponding dithiiranes. X-ray diffraction analysis of 3,3-di(1-adamantyl)dithiirane is reported. Reaction of 34S-labeled 3,3-di(1-adamantyl)dithiirane 1-oxide with LR produced the corresponding dithiirane in which the 34S atoms were retained quantitatively.