Density, Viscosity, and Refractive Index of Aqueous
CO2‑Loaded and -Unloaded Ethylaminoethanol (EAE) Solutions from 293.15 to 323.15 K for Post Combustion CO2 Capture
posted on 2017-11-01, 11:34authored byHongxia Gao, Ge Gao, Helei Liu, Xiao Luo, Zhiwu Liang, Raphael O. Idem
The
physical properties of densities, viscosities, and refractive
indices, which are important in kinetics and mass transfer processes
were measured for aqueous CO2-loaded and -unloaded (EAE)
solutions applied in CO2 absorption in the temperature
range from 293.15 to 323.15 K at atmospheric pressure. Due to the
limitation of the instrument and corrosive behavior with increasing
concentration, the mass fractions (w1)
of aqueous EAE solutions selected were: as 0.089, 0.178, 0.267, and
0.356, which correspond to the molar concentrations of 1, 2, 3, and
4 mol·L–1, respectively. The determined density,
viscosity and refractive index data for binary EAE+H2O
and ternary CO2+EAE+H2O systems were correlated
using Weiland et al. model, Redlich–Kister equation, extended
Arrhenius equation, and a new proposed empirical function. All the
calculated density, viscosity, and refractive index data fitted well
with experimental values at all operational conditions.