Defect Rich UiO-66 with Enhanced Adsorption and Photosensitized Reduction of Cr(VI) under Visible Light

Photosensitization is a promising way to make UiO-66 visible light responsive. In this work, zirconium (Zr) precursors and synthetic methods (solvent-assisted or nonsolvent-assisted) were found to significantly affect the electric charge and the defect sites of UiO-66. UiO-66 with enhanced adsorption and photosensitized photocatalytic ability was then obtained. When ZrOCl₂·8H₂O was applied as Zr-precursor in a nonsolvent method, defect rich UiO-66 (UiO–OCl–N) was achieved with higher Cr­(VI) adsorbing ability and improved photosensitized photocatalytic ability. Moreover, with the coexistence of Rhodamine B in Cr­(VI) solution, photocatalytic performance of UiO-66 can be further enhanced.