American Chemical Society
ol302201q_si_001.pdf (4.39 MB)

Cyclizative Atmospheric CO2 Fixation by Unsaturated Amines with t‑BuOI Leading to Cyclic Carbamates

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journal contribution
posted on 2012-09-21, 00:00 authored by Youhei Takeda, Sota Okumura, Saori Tone, Itsuro Sasaki, Satoshi Minakata
A cyclizative atmospheric CO2 fixation by unsaturated amines such as allyl and propargyl amines under mild reaction conditions, efficiently leading to cyclic carbamates bearing a iodomethyl group, have been developed utilizing tert-butyl hypoiodite (t-BuOI).