Cp*CoIII-Catalyzed Dehydrative C–H Allylation of 6‑Arylpurines and Aromatic Amides Using Allyl Alcohols in Fluorinated Alcohols

Bunno, Youka; Murakami, Nanami; Suzuki, Yudai; Kanai, Motomu; Yoshino, Tatsuhiko; Matsunaga, Shigeki

doi:10.1021/acs.orglett.6b00846.s001

ol6b00846_si_001.pdf (2.63 MB)

Cp*Co^III-Catalyzed Dehydrative C–H Allylation of 6‑Arylpurines and Aromatic Amides Using Allyl Alcohols in Fluorinated Alcohols

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posted on 2016-04-27, 12:36 authored by Youka Bunno, Nanami Murakami, Yudai Suzuki, Motomu Kanai, Tatsuhiko Yoshino, Shigeki Matsunaga

Cp*Co^III-catalyzed C–H allylation of various aromatic C–H bonds using allyl alcohols as allylating reagents is described. Improved reaction conditions using fluorinated alcohol solvents afforded efficient directed C–H allylation of 6-arylpurines, benzamides, and a synthetically useful Weinreb amide with good functional group compatibility.

Cp*Co^III-Catalyzed Dehydrative C–H Allylation of 6‑Arylpurines and Aromatic Amides Using Allyl Alcohols in Fluorinated Alcohols

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