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Cp*CoIII-Catalyzed Dehydrative C–H Allylation of 6‑Arylpurines and Aromatic Amides Using Allyl Alcohols in Fluorinated Alcohols

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posted on 27.04.2016, 12:36 authored by Youka Bunno, Nanami Murakami, Yudai Suzuki, Motomu Kanai, Tatsuhiko Yoshino, Shigeki Matsunaga
Cp*CoIII-catalyzed C–H allylation of various aromatic C–H bonds using allyl alcohols as allylating reagents is described. Improved reaction conditions using fluorinated alcohol solvents afforded efficient directed C–H allylation of 6-arylpurines, benzamides, and a synthetically useful Weinreb amide with good functional group compatibility.

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