tz0c00108_si_001.pdf (3.3 MB)
Covalently Functionalized MoS2 with Dithiolenes
journal contribution
posted on 2020-06-19, 19:04 authored by Ioanna
K. Sideri, Raul Arenal, Nikos TagmatarchisAdvances
are required to develop functionalization routes for MoS2, in both the metallic 1T and semiconducting 2H phase, that
will not only enable their easier manipulation and handling in liquid
media but also enhance their applicability in diverse technological
fields. Herein, we report an original functionalization methodology
for covalently incorporating dithiolene units at the periphery of
exfoliated 1T- and 2H-MoS2 sheets, by employing a bis(thiolate)
salt as a ligand in a green and facile protocol. Extensive characterization
of the covalently functionalized materials is presented, along with
a pathway for the à la carte chemical manipulation of MoS2. Markedly, the reported methodology may be applied for modifying other transition metal dichalcogenides.