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Copper-Mediated Cross-Coupling of H-Phosphonates with Vinyliodonium Salts: A Novel Very Mild Synthesis of 2-Arylvinylphosphonates

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journal contribution
posted on 17.02.2005, 00:00 by Sabine Thielges, Philippe Bisseret, Jacques Eustache
We report a novel, very mild, highly stereoselective preparation of 2-arylvinylphosphonates at room temperature that involves the copper iodide-mediated cross-coupling of H-phosphonates with vinyliodonium tetrafluoroborates.