Version 2 2020-01-24, 16:07Version 2 2020-01-24, 16:07
Version 1 2020-01-24, 15:35Version 1 2020-01-24, 15:35
journal contribution
posted on 2020-01-24, 16:07authored byCorentin Rasson, Olivier Riant
Herein
we report the synthesis of a family of copper(I) diphosphine
bifluoride complexes, their characterization, and their use as efficient
preactivated catalysts for nucleophilic copper addition of pronucleophiles
on unsaturations. Their use as mechanistic probes is also highlighted
by the identification of two copper deuterides.