ol7b02911_si_001.pdf (2.55 MB)
Copper-Catalyzed C(sp2)–S Coupling Reactions for the Synthesis of Aryl Dithiocarbamates with Thiuram Disulfide Reagents
journal contribution
posted on 2017-10-16, 19:41 authored by Zhi-Bing Dong, Xing Liu, Carsten BolmAn
efficient protocol for the copper-catalyzed preparation of aryl
dithiocarbamates from aryl iodides and inexpensive, environmentally
benign tetraalkylthiuram disulfides was developed. The features of
mild reaction conditions, high yields, and broad substrate scope render
this new approach synthetically attractive for the preparation of
potentially biologically active compounds.