posted on 2024-01-10, 19:10authored byHao Lin, Yangyang Chen, Junlang Huo, Li Du
To
facilitate the extensive adoption of proton exchange
membrane
fuel cells (PEMFCs), it is important to address the issues of electrochemical
corrosion and weak interaction with platinum (Pt) caused by the carbon
support. Herein, a strong metal–support interaction (SMSI)
effect was constructed with Pt nanoparticles loaded in porous chromium
nitride (CrN) nanogrids (labeled as Pt/CrN). The porous CrN nanogrids
are synthesized via a Maillard nitridation method, and better support
size was obtained by controlling the average diameter of CrN nanoparticles
by adjusting the proportion of precursors in the oxide preparation.
Electrochemical tests establish that Pt/CrN is a stable oxygen reduction
reaction catalyst with half-wave potential attenuated by only 4.5
mV after accelerated durability tests, which can be a result of the
SMSI effect between Pt and CrN. Moreover, CrN was shown to modulate
the ionomer distribution in the catalyst layer (CL). Further investigations
have revealed that CrN remains stable up to 1.2 V but degrades significantly
above 1.4 V. This work not only broadens the spectrum of Pt-based
catalyst support options but also provides insights into the engineering
of the SMSI effect. This knowledge will benefit the future design
of transition metal nitride for PEMFCs and other technologies.