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Conformal Encapsulation of Silver Nanowire Transparent Electrodes by Nanosized Reduced Graphene Oxide Leading to Improved All-Round Stability

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posted on 2022-07-21, 08:44 authored by Woo Hyun Chae, Jatin J. Patil, Jeffrey C. Grossman
Solution-processed silver nanowire (AgNW) networks are promising as next-generation transparent conductive electrodes due to their excellent optoelectronic properties, mechanical flexibility, as well as low material and processing costs. However, AgNWs are prone to thermally induced fragmentation and chemical degradation, necessitating a conformal protective coating typically achieved by low-throughput methods such as sputtering or atomic layer deposition. Herein, we report a facile all-solution-based approach to synthesize a conformally coated AgNW network by nanosized reduced graphene oxide R­(nGO). In this method, probe ultrasonication is used to obtain nanosized GO, which is coated on AgNWs by a layer-by-layer approach and then chemically treated to form R­(nGO)/AgNW. We show that our transparent electrode has excellent transmittance (85–92%) and sheet resistance (17.5 Ω/sq), combined with outstanding thermal and electrothermal stability, thanks to the conformal nature of the R­(nGO) film, and demonstrate its use as a transparent heater with a high maximum temperature. This, in conjunction with improved long-term chemical and mechanical bending stability of R­(nGO)/AgNW, indicates that our newly developed process represents an effective and low-cost strategy to improve the overall operational resilience of metal nanowire-based transparent conductive electrodes.

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