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Configurational Ordering of Cationic Chiral Dyes Using a Novel C2-Symmetric Hexacoordinated Phosphate Anion

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journal contribution
posted on 2000-11-23, 00:00 authored by Jérôme Lacour, Anne Londez, Catherine Goujon-Ginglinger, Volker Buss, Gérald Bernardinelli
C2-Symmetry hexacoordinated phosphorus BINPHAT anionof configuration controlled by a BINOL ligandcan be prepared readily in a one-pot process and behaves as an efficient NMR chiral shift agent and chiral inducer onto monomethinium dyes (CD, 1H NMR).

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