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Cleavage of Carbon–Carbon Triple Bond: Direct Transformation of Alkynes to Nitriles

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journal contribution
posted on 07.06.2013, 00:00 by Noriko Okamoto, Minoru Ishikura, Reiko Yanada
A new cleavage reaction of carbon–carbon triple bonds proceeds efficiently with NIS and TMSN3, giving the corresponding nitriles in moderate to good yields.