Chlorine-35 Solid-State NMR Spectroscopy as an Indirect Probe of Germanium Oxidation State and Coordination Environment in Germanium Chlorides
journal contribution
posted on 2014-07-21, 00:00 authored by Margaret A. Hanson, Victor V. Terskikh, Kim M. Baines, Yining HuangDue
to the prevalence of Ge–Cl bonds in germanium chemistry and
the inherent challenges of germanium-73 NMR spectroscopy, chlorine-35
NMR spectroscopy was investigated as an indirect method of characterization
for these ubiquitous and useful compounds. Chlorine-35 NMR parameters
were correlated with structural metrics as well as the oxidation state
of germanium.
