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Chiral Phthalocyanines through Axial Coordination

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journal contribution
posted on 20.04.2018, 16:49 by Dora M. Răsădean, Tiberiu M. Gianga, Alexander H. Swan, Gabriele Kociok-Köhn, G. Dan Pantoş
A novel approach to axially induce chirality on silicon phthalocyanines via a microwave-assisted route is reported. CD analysis provides spectroscopic evidence that chirality is transferred onto both Soret and Q-bands of the phthalocyanine core. A chiral naphthalenediimide ligand was found to induce the largest Cotton effect on the macrocycle absorptions.