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Chiral Molecular Ferromagnets Based on Copper(II) Polymers with End-On Azido Bridges

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journal contribution
posted on 12.11.2007, 00:00 authored by Zhi-Guo Gu, You Song, Jing-Lin Zuo, Xiao-Zeng You
Two homochiral two-dimensional brick-wall complexes with only end-on azido bridges, [Cu3((R)-phea)2(N3)6]n (1) and [Cu3((S)-phea)2(N3)6]n (2) (phea = 1-phenylethylamine), have been synthesized and structurally characterized. Magnetic studies show that both complexes are chiral ferromagnets with the magnetic transition temperature at 5.5 K.