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Chemoselectivity of the Ruthenium-Catalyzed Hydrative Diyne Cyclization:  Total Synthesis of (+)-Cylindricine C, D, and E

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journal contribution
posted on 2003-11-27, 00:00 authored by Barry M. Trost, Michael T. Rudd
The chemoselectivity of the ruthenium-catalyzed hydrative diyne cylization is explored in an expeditious synthesis of the tricyclic alkaloids cylindricine C, D, and E.