Chemical Surface Adsorption and Trace Detection of Alcohol Gas in Graphene Oxide-Based Acid-Etched SnO₂ Aerogels

An acidified SnO₂/rGO aerogel (ASGA) is an attractive contributor in ethanol gas sensing under ultralow concentration because of the sufficient active sites and adsorption pores in SnO₂ and the rGA, respectively. Furthermore, a p–n heterojunction is successfully constructed by the high electron mobility between ASP and rGA to establish a brand-new bandgap of 2.72 eV, where more electrons are released and the surface energy is decreased, to improve the gas sensitivity. The ASGA owns a specific surface area of 256.1 m²/g, far higher than SnO₂ powder (68.7 m²/g), indicating an excellent adsorption performance, so it can acquire more ethanol gas for a redox reaction. For gas-sensing ability, the ASGA exhibits an excellent response of R_a/R_g = 137.4 to 20 ppm of ethanol at the optimum temperature of 210 °C and can reach a response of 1.2 even at the limit detection concentration of 0.25 ppm. After the concentration gradient change test, a nonlinear increase between concentration and sensitivity (S–C curve) is observed, and it indirectly proves the chemical adsorption between ethanol and ASGA, which exhibits charge transfer and improves electron mobility. In addition, a detailed energy band diagram and sensor response diagram jointly depict the gas-sensitive mechanism. Finally, a conversed calculation explains the feasibility of the nonlinear S–C curve from the atomic level, which further verifies the chemical adsorption during the sensing process.