Cerium(IV) Ammonium Nitrate Mediated Three-Component
α‑Allylation of Imine Surrogates

Bekkaye, Mathieu; Masson, Géraldine

doi:10.1021/ol5004143.s001

Cerium(IV) Ammonium Nitrate Mediated Three-Component α‑Allylation of Imine Surrogates

journal contribution

posted on 2014-03-07, 00:00 authored by Mathieu Bekkaye, Géraldine Masson

A general and practical CAN-mediated oxidative radical α-coupling reaction of various imine surrogates with allylsilanes has been described. This multicomponent process affords β-allylated α-carbamido ethers as stable imine precursors in respectable yields under mild conditions.