ja066401h_si_002.pdf (287.82 kB)

Cationic Zinc Enolates as Highly Active Catalysts for Acrylate Polymerization

Download (287.82 kB)
journal contribution
posted on 22.11.2006, 00:00 by Logan E. Garner, Hongping Zhu, Mark L. Hlavinka, John R. Hagadorn, Eugene Y.-X. Chen
Unprecedented cationic zinc enolates have been generated by a novel activation route involving the amido to imino ligand transformation with B(C6F5)3, structurally characterized, and utilized as highly active catalysts for the production of high molecular weight polyacrylates at ambient temperature.