Cationic Palladium(II)-Catalyzed Highly
Enantioselective [3 + 2] Annulation of
2-Acylarylboronic Acids with Substituted
Alkynes

Yang, Miao; Zhang, Xumu; Lu, Xiyan

doi:10.1021/ol702503e.s002

ol702503e_si_002.pdf (1.97 MB)

Cationic Palladium(II)-Catalyzed Highly Enantioselective [3 + 2] Annulation of 2-Acylarylboronic Acids with Substituted Alkynes

journal contribution

posted on 2007-11-22, 00:00 authored by Miao Yang, Xumu Zhang, Xiyan Lu

A cationic palladium(II)-catalyzed enantioselective tandem [3 + 2] annulation of 2-acylarylboronic acids with substituted alkynes to yield optically active 1-indenols was developed in high yields and excellent enantioselectivities.

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Keywords

Enantioselective annulation AlkynesA Cationic Annulation yield acid enantioselective cationic Substituted Palladium enantioselectivitie indenol Acylarylboronic tandem palladium acylarylboronic alkyne Acid

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