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Carbon−Sulfur Bond Formation via Iridium-Catalyzed Asymmetric Allylation of Aliphatic Thiols

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journal contribution
posted on 18.03.2011, 00:00 by Ning Gao, Shengcai Zheng, Weikang Yang, Xiaoming Zhao
An iridium-catalyzed regio- and enatioselective allylation with aliphatic thiols as the nucleophile in dichloromethane has been accomplished; and the branch products were obtained in 34−80% yields with up to 94/6 b/l and 98% ee.

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