ol200197v_si_001.pdf (3.82 MB)
Download file

Carbon−Sulfur Bond Formation via Iridium-Catalyzed Asymmetric Allylation of Aliphatic Thiols

Download (3.82 MB)
journal contribution
posted on 18.03.2011, 00:00 authored by Ning Gao, Shengcai Zheng, Weikang Yang, Xiaoming Zhao
An iridium-catalyzed regio- and enatioselective allylation with aliphatic thiols as the nucleophile in dichloromethane has been accomplished; and the branch products were obtained in 34−80% yields with up to 94/6 b/l and 98% ee.