Carbon Networks Based on
Dehydrobenzoannulenes. 3. Synthesis of
Graphyne Substructures1

Kehoe, Joshua M.; Kiley, James H.; English, Jamieson J.; Johnson, Charles A.; Petersen, Ryan C.; Haley, Michael M.

doi:10.1021/ol005623w.s001

Carbon Networks Based on Dehydrobenzoannulenes. 3. Synthesis of Graphyne Substructures¹

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posted on 2000-03-11, 00:00 authored by Joshua M. Kehoe, James H. Kiley, Jamieson J. English, Charles A. Johnson, Ryan C. Petersen, Michael M. Haley

This Letter describes the synthesis of the first macrobicyclic subunits of the hypothetical all-carbon network graphyne. Key to synthetic success is an intramolecular Sonogashira cross-coupling sequence.

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sequence Sonogashira intramolecular 3. Synthesis synthesis graphyne Graphyne Substructures 1 carbon Networks Dehydrobenzoannulene macrobicyclic subunits

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Carbon Networks Based on Dehydrobenzoannulenes. 3. Synthesis of Graphyne Substructures¹

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Carbon Networks Based on Dehydrobenzoannulenes. 3. Synthesis of Graphyne Substructures1

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Carbon Networks Based on Dehydrobenzoannulenes. 3. Synthesis of Graphyne Substructures¹