posted on 2024-01-20, 14:07authored byDipa Dutta Pathak, Apurav Guleria, Jitendra Nuwad, Anil Krishna Debnath, Avesh K. Tyagi, V. Grover
The quest for better alternatives for graphite anodes
is the holy
grail in the field of energy storage technologies. Biomass-derived
carbon has been widely explored as the energy-dense and cost-effective
option but involves several pre/post-conditioning steps. In this study,
kitchen chemistry concepts of fermentation have been utilized to obtain
sustainable carbon anodes from readily available and cost-effective
wheat flour and baker’s yeast. The yeast-fermented mixture
of wheat flour and MnCO3 is pyrolyzed under 500 °C
to yield porous C-MnO composites, which have been explored as an anode
for Li-ion batteries. The material showed superior electrochemical
performance with an initial discharge of 1160 mAh g–1 at 0.15 A g–1 (after solid electrolyte interface
formation). A reversible capacity of 1499 mAh g–1 was obtained with a concomitant improvement of 30% after 160 cycles
exhibiting a “negative fading effect”. Excellent electrochemical
behavior has been attributed to the synergistic effect of in situ synthesized, well-dispersed MnO in carbon, the presence
of redox-active Mn, and well-connected porosity in nanohybrids. At
a high current density of 1 A g–1, the anode displayed
an exemplary initial discharge capacity of 770 mAh g–1 with a high initial Coulombic efficiency of 90%, which was maintained
at 856 mAh g–1 after 760 cycles. Easy synthesis
and excellent electrochemical performance render this material highly
promising for battery applications.