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Carbon−Hydrogen Bond Activation of Aromatic Imines by (Cp*2SmH)2

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journal contribution
posted on 17.09.1996, 00:00 by Nora S. Radu, Stephen L. Buchwald, Brian Scott, Carol J. Burns
Treatment of (Cp*2SmH)2 with 2-phenyl-1-pyrroline forms product 1, via ortho-metalation. Complex 1 was characterized spectroscopically and by single-crystal X-ray diffraction. The C−H bond activation reaction also occurs for acyclic aromatic ketimines and aldimines.