Capping Efficiency of
Various Carbonaceous and Mineral
Materials for In Situ Remediation of Polychlorinated
Dibenzo-p-dioxin and Dibenzofuran Contaminated Marine
Sediments: Sediment-to-Water Fluxes and Bioaccumulation in Boxcosm
Tests
posted on 2012-03-20, 00:00authored bySarah Josefsson, Morten Schaanning, Göran S. Samuelsson, Jonas S. Gunnarsson, Ida Olofsson, Espen Eek, Karin Wiberg
The efficiency of thin-layer capping in reducing sediment-to-water
fluxes and bioaccumulation of polychlorinated dibenzo-p-dioxins and dibenzofurans, hexachlorobenzene, and octachlorostyrene
was investigated in a boxcosm experiment. The influence of cap thickness
(0.5–5 cm) and different cap materials was tested using a three-factor
experimental design. The cap materials consisted of a passive material (coarse or fine limestone or a marine clay) and an active material (activated carbon (AC) or kraft lignin)
to sequester the contaminants. The cap thickness and the type of active
material were significant factors, whereas no statistically significant
effects of the type of passive material were observed. Sediment-to-water
fluxes and bioaccumulation by the two test species, the surface-dwelling Nassarius nitidus and the deep-burrowing Nereis spp., decreased with increased cap thickness
and with addition of active material. Activated carbon was more efficient
than lignin, and a ∼90% reduction of fluxes and bioaccumulation
was achieved with 3 cm caps with 3.3% AC. Small increases in fluxes
with increased survival of Nereis spp.
indicated that bioturbation by Nereis spp. affected the fluxes.