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Borane-Catalyzed Hydrosilylation of Thiobenzophenone:  A New Route to Silicon−Sulfur Bond Formation

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journal contribution
posted on 28.03.2005, 00:00 authored by Daniel J. Harrison, Robert McDonald, Lisa Rosenberg
Clean and quantitative B(C6F5)3-catalyzed hydrosilylation of thiobenzophenone by a variety of mono- and disilanes proceeds under mild conditions, at low catalyst loading, to furnish new silyl thioether compounds.