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Bench-Stable Nickel Precatalysts with Heck-type Activation

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journal contribution
posted on 09.08.2018, 17:33 by Jessica M. Weber, Ashley R. Longstreet, Timothy F. Jamison
Herein, we report the synthesis and characterization of a new class of air- and moisture-stable phosphine-containing nickel­(II) precatalysts, which activate through a Heck-type mechanism. The activities of the precatalysts are demonstrated with a carbonyl–ene coupling reaction.