posted on 2016-01-13, 00:00authored byVikas Narayan, Peter Arendt Jensen, Ulrik Birk Henriksen, Helge Egsgaard, Rasmus Glar Nielsen, Peter Glarborg
A low-temperature circulating fluidized
bed system (LTCFB) gasifier allows for pyrolysis and gasification
to occur at low temperatures, thereby improving the retention of alkali
and other inorganic elements within the system and minimizing the
amount of ash species in the product gas. In addition, the low reactor
temperature ensures that high-alkali biomass fuels can be used without
risk of bed defluidization. This paper presents the first investigation
of the fate of alkali metals and ash in low-temperature gasifiers.
Measurements on bed material and product gas dust samples were made
on a 100 kW and a 6 MW LTCFB gasifier. Of the total fuel ash entering
the system, the largest fraction (40–50%) was retained in the
secondary cyclone bottoms, while a lower amount (8–10%) was
released as dust in the exit gas. Most of the alkali and alkaline
earth metals were retained in the solid ash, along with Si and a minor
fraction of Cl. Most Cl and S were released in gaseous form, with
chlorine partly as methyl chloride. The tar in the product gas from
the LTCFB gasifier contained only negligible amounts of potassium
and other inorganic elements. The release of condensed ash species
from the system was controlled by the particle size and the cut size
of the primary and secondary cyclones. A model accounting for the
ash collection by the plant cyclones was shown to predict the product
gas ash particle release reasonably well.