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Base-Promoted Consecutive Enolate Addition Reaction of [60]Fullerene with Ketones

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journal contribution
posted on 06.11.2015, 00:00 by Si Chen, Zong-Jun Li, Shu-Hui Li, Xiang Gao
[60]­Fullerene derivatives with novel 1,4,9,25- and 1,4,9,12-configurations were obtained by reactions of C60 with aliphatic ketones and benzyl bromide under basic conditions. The structures of the products were determined by X-ray single-crystal diffraction and spectroscopic characterization. The reactions were rationalized by a monoenolate addition experiment and in situ vis–NIR spectroscopy.