ol000068j_si_001.pdf (206.96 kB)
Download file

Baeyer−Villiger Oxidation Promoted by Reaction of Peracids with Cyclic Oxocarbenium Ions Generated in Situ from Internal Hemiketals

Download (206.96 kB)
journal contribution
posted on 18.05.2000, 00:00 by Kevin W. Hunt, Paul A. Grieco
Reactive cyclic oxocarbenium ions, generated in situ from internal hemiketals, undergo Baeyer−Villiger oxidation upon exposure to m-chloroperbenzoic acid leading, after hydrolysis of the resultant lactones, to acyclic fragments for use in natural product synthesis.