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Baeyer−Villiger Oxidation Promoted by Reaction of Peracids with Cyclic Oxocarbenium Ions Generated in Situ from Internal Hemiketals

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journal contribution
posted on 18.05.2000, 00:00 by Kevin W. Hunt, Paul A. Grieco
Reactive cyclic oxocarbenium ions, generated in situ from internal hemiketals, undergo Baeyer−Villiger oxidation upon exposure to m-chloroperbenzoic acid leading, after hydrolysis of the resultant lactones, to acyclic fragments for use in natural product synthesis.

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