American Chemical Society
jo4025573_si_001.pdf (2.5 MB)

BF3·Et2O‑Catalyzed Formal [3 + 2] Reaction of Aziridinofullerenes with Carbonyl Compounds

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journal contribution
posted on 2014-02-07, 00:00 authored by Hai-Tao Yang, Meng-Lei Xing, Ye-Fei Zhu, Xiao-Qiang Sun, Jiang Cheng, Chun-Bao Miao, Fa-Bao Li
The BF3·Et2O-catalyzed formal [3 + 2] reaction of aziridinofullerenes with various carbonyl compounds for the easy preparation of fullerooxazolidines has been developed. Moreover, the reaction of aziridinofullerene with ethyl formate affords the simplest fullerooxazole without substituent.