Autoxidation of Formaldehyde with OxygenA Comparison of Reaction Channels

The autoxidation of formaldehyde through initiation by triplet oxygen is studied via two initial steps: (1) H-atom abstraction and (2) ³O₂ addition reaction. The reaction energy profiles show that the reactions are thermodynamically and kinetically demanding. A comparison of the pathways of these initial reactions and the search for a less energy-demanding pathway is presented. The presence of a Brønsted acid has no effect on the energetics of the reaction, while the presence of a single water molecule catalyst enhances the initial reactions. The H-atom abstraction reaction from formaldehyde results in formyl and hydroperoxy radicals. These radicals on further reaction with the second equivalent of ³O₂ lead to a CO + 2HO₂ product channel. The ³O₂ addition reaction to formaldehyde results in a triplet biradical intermediate which further leads to performic acid, the precursor in the synthesis of carboxylic acids from aldehydes. In the presence of water molecules, performic acid is formed in a single kinetic step, and this leads to a CO₂ + OH + HO₂ product channel upon subsequent reaction with ³O₂ in a thermodynamically favorable reaction. The results show that the less established ³O₂ addition reaction to aldehydes is a viable route for autoxidation in the absence of purpose-built initiators, in addition to the well-established H-atom abstraction route.