posted on 2020-12-23, 14:04authored byAydar Irmikimov, Liliany N. Pamasi, Azusa N. Hattori, Takaaki Higashi, Shunta Takahashi, Emilia E. Hashamova, Xiaoqian Shi, Fangzhun Guo, Nobuyoshi Hosoito, Ai I. Osaka, Hidekazu Tanaka, Ken Hattori
The
control of three-dimensional (3D) geometrical shapes is one
of important approaches that contribute the development of new functionalities
in material science. We produced 3D Si pyramids with atomically flat
and reconstructed {111} facet surfaces supporting atomically resolved
material growth in 3D space for the first time. The complex 4-fold
clean 7×7 and 2×2-Fe low-energy electron diffraction (LEED)
patterns reflecting the pyramidal geometry showed the realization
of atomically reconstructed facet surfaces on the 3D patterned Si.
Cross-sectional transmission electron microscopy (TEM) revealed the
epitaxial heterointerfaces between Fe nanofilm and Si facet surfaces.
The LEED and TEM results indicate the applicability of the Si pyramid
as a supporting substrate for arbitrarily oriented 3D functional structures.
The pyramidal Fe nanofilm displayed magnetic properties depending
on the geometric shape, owing to the facet surfaces and the sharp
facet edges. The unique anisotropic magnetization behavior of the
3D pyramid shape indicates that the epitaxial growth of an arbitrary
geometry by virtue of the atomically ordered substrate surfaces in
3D space can contribute to the modification of the functionality.